𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Photochemical reactions of Group 6 metal carbonyls with alkenes

✍ Scribed by Teresa Szymańska-Buzar


Book ID
104010899
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
375 KB
Volume
250
Category
Article
ISSN
0010-8545

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Reactions of 1,1,2,2-tetramethyldisilane
✍ Robert C. Kerber; Tuula Pakkanen 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 507 KB

I,I,2,2-Tetramethyldisilane reacts with Fez(CO)9 to yield bis(u-dimethylsilylene)-u-car-bony1 bis(tricar-bonylironJ(Fe-Fe). Reaction with octacarbonyldicobalt analogously gives bis(u-dimethylsilylene)bis-(tricarbonylcobalt)(Co-Co) as stable product; spectroscopic results also indicate inter alia the

Octahedral metal carbonyls. : XXXVII. th
✍ J.E. Pardue; G.R. Dobson 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo