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Reactions of primary phosphines with tetracyclone

โœ Scribed by Y. Kashman; H. Ronen


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
176 KB
Volume
12
Category
Article
ISSN
0040-4039

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The nature of the products from the reaction of TrtPH 2 (1) with an equimolar amount of phosgene strongly depends on the solvent. The initial intermediate 2 was isolated from toluene, but lost CO in dichloromethane, and HCl in diethyl ether, yielding TrtP(H)Cl (3), and (TrtPCO) 2 (4 b), respectively