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Reactions of pivaloin derivatives with lithium tetramethylpiperidide

✍ Scribed by Creary, Xavier

Book ID
127179554
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
947 KB
Volume
45
Category
Article
ISSN
0022-3263

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Recently Magnus and coworkers reported the selective deprotonation of chloromethyltrimethylsilane (1) to the carbanion (1) with sec-butyllithium-TMEDA.l In the presence of aldehydes and ketones, 2 reacted to give a,&epoxysilanes (g), compounds of substantial preparative value.' MeSSiCH2C1 m [MeSSicH