Recently Magnus and coworkers reported the selective deprotonation of chloromethyltrimethylsilane (1) to the carbanion (1) with sec-butyllithium-TMEDA.l In the presence of aldehydes and ketones, 2 reacted to give a,&epoxysilanes (g), compounds of substantial preparative value.' MeSSiCH2C1 m [MeSSicH
β¦ LIBER β¦
Directed metalation of aromatic aldimines with lithium 2,2,6,6-tetramethylpiperidide
β Scribed by Flippin, Lee A.; Muchowski, Joseph M.; Carter, David S.
- Book ID
- 120951101
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 633 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0022-3263
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