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Dipole stabilized carbanions. Reactions of benzoate esters with lithium 2,2,6,6-tetramethylpiperidide

โœ Scribed by Upton, Charles J.; Beak, Peter


Book ID
127306288
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
715 KB
Volume
40
Category
Article
ISSN
0022-3263

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Reaction of chloromethyltrimethylsilane
โœ R.A. Olofson; Dennis H. Hoskin; Kenneth D. Lotts ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 241 KB

Recently Magnus and coworkers reported the selective deprotonation of chloromethyltrimethylsilane (1) to the carbanion (1) with sec-butyllithium-TMEDA.l In the presence of aldehydes and ketones, 2 reacted to give a,&epoxysilanes (g), compounds of substantial preparative value.' MeSSiCH2C1 m [MeSSicH