Reaction of chloromethyltrimethylsilane
โ
R.A. Olofson; Dennis H. Hoskin; Kenneth D. Lotts
๐
Article
๐
1978
๐
Elsevier Science
๐
French
โ 241 KB
Recently Magnus and coworkers reported the selective deprotonation of chloromethyltrimethylsilane (1) to the carbanion (1) with sec-butyllithium-TMEDA.l In the presence of aldehydes and ketones, 2 reacted to give a,&epoxysilanes (g), compounds of substantial preparative value.' MeSSiCH2C1 m [MeSSicH