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Reactions of Phosphorus Compounds. XIII. Kinetics and Mechanism of the Reaction of Triphenylphosphine with α,α-Dihaloamides

✍ Scribed by Speziale, A. J.; Taylor, Lynn J.


Book ID
126446970
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
754 KB
Volume
31
Category
Article
ISSN
0022-3263

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The reaction of α-bromoketones with trip
✍ I.J. Borowitz; L.I. Grossman 📂 Article 📅 1962 🏛 Elsevier Science 🌐 French ⚖ 178 KB

THE reaction of phenacyl halides with triphenylphosphine is known to give the corresponding phenacyltriphenylphosphonium halides via nucleophilic displacement of halogen. 3 We have found that secondary and tertiary abromoketones, in contrast, react with triphenylphosphine in refluxing benzene-methan