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Reaction of Phosphorus Compounds. VI. Kinetics and Mechanism of the Witting Reaction

โœ Scribed by Speziale, A. J.; Bissing, D. E.

Book ID
126277548
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
275 KB
Volume
85
Category
Article
ISSN
0002-7863

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The kinetics of oxidation of N,N-dimethylformamide by chromium(VI) has been studied spectrophotometrically in aqueous perchloric acid media at 20ะŠC. The rate showed a first-order dependence on both [Cr(VI)] and [DMF], and increased markedly with increasing [H ฯฉ ]. The order with respect to [HClO 4 ]