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Kinetics and mechanism of the chromium(VI)-iodide reaction

โœ Scribed by Gaswick, Dennis C.; Krueger, James H.

Book ID
123608665
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
645 KB
Volume
91
Category
Article
ISSN
0002-7863

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The kinetics of oxidation of N,N-dimethylformamide by chromium(VI) has been studied spectrophotometrically in aqueous perchloric acid media at 20ะŠC. The rate showed a first-order dependence on both [Cr(VI)] and [DMF], and increased markedly with increasing [H ฯฉ ]. The order with respect to [HClO 4 ]