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Kinetics and mechanism of the reaction between vanadium(II) and chromium(VI)

โœ Scribed by Bridges, Kenneth L.; Mukherjee, Samir K.; Gordon, Gilbert.

Book ID
126975223
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
811 KB
Volume
11
Category
Article
ISSN
0020-1669

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The kinetics of oxidation of N,N-dimethylformamide by chromium(VI) has been studied spectrophotometrically in aqueous perchloric acid media at 20ะŠC. The rate showed a first-order dependence on both [Cr(VI)] and [DMF], and increased markedly with increasing [H ฯฉ ]. The order with respect to [HClO 4 ]