Stoichiometry of the reaction between iron(II) and chromium(VI)
β Scribed by G.Gopala Rao; U.Murali Krishna
- Book ID
- 118990115
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- English
- Weight
- 330 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0039-9140
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The kinetics of oxidation of N,N-dimethylformamide by chromium(VI) has been studied spectrophotometrically in aqueous perchloric acid media at 20ΠC. The rate showed a first-order dependence on both [Cr(VI)] and [DMF], and increased markedly with increasing [H Ο© ]. The order with respect to [HClO 4 ]
Received 'NovDmlxx zqth, I 969) , '. \* In, view of doubts regarding reaction products, the present study was undertaken .to investigate' the stoichiometry of the reaction between the highly reactive, monofunctional mercurial, MeHgI, and a typical soluble inorganic sulphide, sodium ' sulphide, .in: