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On the Mechanism of the Reactions of α-Bromoketones with Triphenylphosphine

✍ Scribed by Borowitz, Irving J.; Virkhaus, Rein.

Book ID
126918218
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
295 KB
Volume
85
Category
Article
ISSN
0002-7863

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The reaction of α-bromoketones with trip
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✍ I.J. Borowitz; L.I. Grossman 📂 Article 📅 1962 🏛 Elsevier Science 🌐 French ⚖ 178 KB

THE reaction of phenacyl halides with triphenylphosphine is known to give the corresponding phenacyltriphenylphosphonium halides via nucleophilic displacement of halogen. 3 We have found that secondary and tertiary abromoketones, in contrast, react with triphenylphosphine in refluxing benzene-methan