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Reactions of metal carbonyls with the azide anion

โœ Scribed by H. Werner; W. Beck; H. Engelmann


Book ID
114041151
Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
415 KB
Volume
3
Category
Article
ISSN
0020-1693

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## This article describes the formation of carbon-metal bonds by reacting carbonylmetalate ions with fluorocarbons. Complex formation depends on the nucleophilic behavior of the anions, and the susceptibility of fluorocarbons to this form of attack.

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The reaction of metal carbonyl anions with methyl metal carbonyl compounds are grouped into three categories: adduct formation, methyl transfer, and no apparent reaction. The formation of acyl anion adducts was observable only in the reactions of (CO)5MnCH3 with either Mn(C0)5-or Re(C0)5-. The acyl