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Reactions of metal carbonyl anions with methyl organometallic compounds

✍ Scribed by Casey, Charles P.; Cyr, Clifford R.; Anderson, Ronald L.; Marten, David F.

Book ID
127387682
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
909 KB
Volume
97
Category
Article
ISSN
0002-7863

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✦ Synopsis

The reaction of metal carbonyl anions with methyl metal carbonyl compounds are grouped into three categories: adduct formation, methyl transfer, and no apparent reaction. The formation of acyl anion adducts was observable only in the reactions of (CO)5MnCH3 with either Mn(C0)5-or Re(C0)5-. The acyl anion adducts could be trapped by alkylation with CH3OS02F which gave c~s-(CO)~M~M~(CO)~C(OCH~)CH~ and cis-(CO)sMnRe(C0)4C(OHC3)CH3, 8. The latter compound was characterized by X-ray crystallography. The transfer of a methyl group from methyl organometallics to the highly nucleophilic CsHsFe(C0)2-was observed in all cases studied.

πŸ“œ SIMILAR VOLUMES

Nucleophilic Reactions of Metal Carbonyl
Nucleophilic Reactions of Metal Carbonyl Anions with Fluorocarbons
✍ Dr. M. I. Bruce; Prof. F. G. A. Stone πŸ“‚ Article πŸ“… 1968 πŸ› John Wiley and Sons 🌐 English βš– 607 KB

## This article describes the formation of carbon-metal bonds by reacting carbonylmetalate ions with fluorocarbons. Complex formation depends on the nucleophilic behavior of the anions, and the susceptibility of fluorocarbons to this form of attack.