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Methylating Reductive Dimerization of Aromatic Carbonyl Compounds, a Novel Organometallic Reaction

✍ Scribed by Prof. Dr. Thomas Kauffmann; Dr. Jan Jordan; Dipl.-Chem. Karl-Uwe Voss


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
257 KB
Volume
30
Category
Article
ISSN
0044-8249

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ChemInform Abstract: Reductive Pinacol C
✍ A. SVATOS; W. BOLAND πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 2 views

Reductive Pinacol Coupling of Aromatic Carbonyl Compounds Catalytic in Chromium(II). -The pinacol reductive coupling is effectively catalyzed by Cr(II) salts co-reduced with Mn powder. The reaction rate and diastereoselectivity are predominantly controlled by the trialkylsilyl chloride used for acti