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ChemInform Abstract: Reductive Pinacol Coupling of Aromatic Carbonyl Compounds Catalytic in Chromium(II).

✍ Scribed by A. SVATOS; W. BOLAND

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Reductive Pinacol Coupling of Aromatic Carbonyl Compounds Catalytic in Chromium(II). -The pinacol reductive coupling is effectively catalyzed by Cr(II) salts co-reduced with Mn powder. The reaction rate and diastereoselectivity are predominantly controlled by the trialkylsilyl chloride used for activation. Bulky silyl chlorides show higher dl-selectivities, albeit with lower yields. -(SVATOS, A.

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