ChemInform Abstract: Pinacolization and Reduction of Aromatic Carbonyls with Aluminum-KOH.
β Scribed by J. M. KHURANA; A. SEHGAL; A. GOGIA; A. MANIAN; G. C. MAIKAP
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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Reductive Pinacol Coupling of Aromatic Carbonyl Compounds Catalytic in Chromium(II). -The pinacol reductive coupling is effectively catalyzed by Cr(II) salts co-reduced with Mn powder. The reaction rate and diastereoselectivity are predominantly controlled by the trialkylsilyl chloride used for acti
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Aluminum-Mediated Reductive Dimerization of Aromatic Dialdehydes. -The 1,2-diols (II) and (III) of the pinacol coupling reaction with inexpensive aluminum powder are accompanied by minor amounts of polymerization products. -(SAHADE, DANIEL A.
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