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Reaction of metal carbonyl anions with metal carbonyl dimers: thermodynamic and kinetic factors that control the reactions

โœ Scribed by Corraine, M. Shauna.; Atwood, Jim D.


Book ID
127131021
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
500 KB
Volume
10
Category
Article
ISSN
0276-7333

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๐Ÿ“œ SIMILAR VOLUMES


Octahedral metal carbonyls. : XXXVII. th
โœ J.E. Pardue; G.R. Dobson ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo