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Reactions of lithium diorganocuprates(I) with tosylates. II. Stereochemical, kinetic, and mechanistic aspects

✍ Scribed by Johnson, Carl R.; Dutra, Gerard A.

Book ID
120074448
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
778 KB
Volume
95
Category
Article
ISSN
0002-7863

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## Abstract The complexes PdCl~4~^2βˆ’^, PdCl~3~(H~2~O)^βˆ’^, and PdCl~3~(Ac)^2βˆ’^, in rapid equilibrium with each other under the adopted experimental conditions, react with ethylenediamine according to the experimental rate law A reaction scheme is proposed involving the reaction of enH^+^ with each