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Kinetic and mechanistic study of the reactions of palladium(II) chlorocomplexes with ethylenediamine in aqueous acid medium

✍ Scribed by D. J. A. De Waal; W. Robb

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
456 KB
Volume
6
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The complexes PdCl~4~^2−^, PdCl~3~(H~2~O)^−^, and PdCl~3~(Ac)^2−^, in rapid equilibrium with each other under the adopted experimental conditions, react with ethylenediamine according to the experimental rate law

A reaction scheme is proposed involving the reaction of enH^+^ with each of the above species, and the specific rate constants are computed. The activation parameters are given.

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