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Reactions of Thiols with Sulfoxides. II. Kinetics and Mechanistic Implications

โœ Scribed by Wallace, Thomas J.; Mahon, John J.

Book ID
121425683
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
552 KB
Volume
86
Category
Article
ISSN
0002-7863

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Kinetics of OH reactions with aliphatic
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โœ P. H. Wine; R. J. Thompson; D. H. Semmes ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 619 KB

The kinetics of OH reactions with 1-4 carbon aliphatic thiols have been investigated over the temperature range 252-430 K. OH radicals were produced by flash photolysis of water vapor at h > 165 nm and detected by time-resolved resonance fluorescence spectroscopy. All thiols investigated react with