Lithium N-butyl-4-pentenylamide (k) ln tetrahydrofuran at 22 'C rearranged smoothly to give a mixture (after protonatlon) of 1-butyl-Z-methylpyrrolldlne, formed by an unusual cyclization process, and cls-and trans-N-butyl-3-pentenylamine, in the presence of 2 0 molar equiv of hexam?i%ylphosphoramlde
โฆ LIBER โฆ
Reactions of hydrazides and hydrazones with n-butyl-lithium
โ Scribed by Barton, Derek H. R.; Lukacs, Gabor; Wagle, Dilip
- Book ID
- 120974708
- Publisher
- The Royal Society of Chemistry
- Year
- 1982
- Tongue
- English
- Weight
- 157 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0022-4936
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Isomerization reactions of lithium N-but
โ
Martin Newcomb; Michael T. Burchill
๐
Article
๐
1982
๐
Elsevier Science
๐
French
โ 233 KB
Reaction of t-butyl lithium with (ยฑ)-3-m
โ
Erno Mohacsi; Roxana Yang; John Blount
๐
Article
๐
1987
๐
Journal of Heterocyclic Chemistry
๐
English
โ 193 KB
Addition and metallation in the reaction
โ
D.J. Booth; B.W. Rockett
๐
Article
๐
1967
๐
Elsevier Science
๐
French
โ 196 KB
A number of N,N-dialhylarylmethylamiues including beasyldimethylamine (2), dimethylaminomethylferrocene (I), (3), N-(ferrocenylmethyl)piperidine (4), and N-(ferrocenylmethyl)pyrrolidine (4), have been shown to undergo specific 2-lithiation by n-butyl-lithium in ether-herane. Thus the amine (I) gave
The reactions of 1,3-diphenylalk-1-enes
โ
Burley, J. W.; Young, R. N.
๐
Article
๐
1971
๐
The Royal Society of Chemistry
๐
English
โ 444 KB
Notes - Metalation of 1-Methylbenzimidaz
โ
Alley, Peggy; Shirley, David
๐
Article
๐
1958
๐
American Chemical Society
๐
English
โ 399 KB
Photochemical degradation of polyepichlo
โ
M.A Majid; M.H George; J.A Barrie
๐
Article
๐
1982
๐
Elsevier Science
๐
English
โ 433 KB