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Reactions of hydrazides and hydrazones with n-butyl-lithium

โœ Scribed by Barton, Derek H. R.; Lukacs, Gabor; Wagle, Dilip


Book ID
120974708
Publisher
The Royal Society of Chemistry
Year
1982
Tongue
English
Weight
157 KB
Volume
8
Category
Article
ISSN
0022-4936

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๐Ÿ“œ SIMILAR VOLUMES


Isomerization reactions of lithium N-but
โœ Martin Newcomb; Michael T. Burchill ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 233 KB

Lithium N-butyl-4-pentenylamide (k) ln tetrahydrofuran at 22 'C rearranged smoothly to give a mixture (after protonatlon) of 1-butyl-Z-methylpyrrolldlne, formed by an unusual cyclization process, and cls-and trans-N-butyl-3-pentenylamine, in the presence of 2 0 molar equiv of hexam?i%ylphosphoramlde

Addition and metallation in the reaction
โœ D.J. Booth; B.W. Rockett ๐Ÿ“‚ Article ๐Ÿ“… 1967 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 196 KB

A number of N,N-dialhylarylmethylamiues including beasyldimethylamine (2), dimethylaminomethylferrocene (I), (3), N-(ferrocenylmethyl)piperidine (4), and N-(ferrocenylmethyl)pyrrolidine (4), have been shown to undergo specific 2-lithiation by n-butyl-lithium in ether-herane. Thus the amine (I) gave