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Notes - Metalation of 1-Methylbenzimidazole with n-Butyl-lithium

โœ Scribed by Alley, Peggy; Shirley, David


Book ID
126061539
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
399 KB
Volume
23
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


Addition and metallation in the reaction
โœ D.J. Booth; B.W. Rockett ๐Ÿ“‚ Article ๐Ÿ“… 1967 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 196 KB

A number of N,N-dialhylarylmethylamiues including beasyldimethylamine (2), dimethylaminomethylferrocene (I), (3), N-(ferrocenylmethyl)piperidine (4), and N-(ferrocenylmethyl)pyrrolidine (4), have been shown to undergo specific 2-lithiation by n-butyl-lithium in ether-herane. Thus the amine (I) gave