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Reactions of Halogen Oxides Studied by Flash Photolysis. II. The Flash Photolysis of Chlorine Monoxide and of the ClO Free Radical

✍ Scribed by Basco, N.; Dogra, S. K.


Book ID
120151617
Publisher
The Royal Society
Year
1971
Tongue
English
Weight
770 KB
Volume
323
Category
Article
ISSN
0962-8444

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The kinetics of ClO formation in the fla
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The production o f C l 0 0 and C10 radicals following the flash photolysis of chlorine + oxygen mixtures has been studied. For the mechanism the following kinetic parameters were measured: and k:,/c(C100; 250 nm) = 9.7 x 105 cm/sec. Then h:3 = 5.9 X lo9 l/mol.sec, h2 = 1.0 X 10" limol-sec, and t(C