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Study of the recombination of chlorine atoms by flash photolysis

✍ Scribed by H. Hippler; J. Troe

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
243 KB
Volume
19
Category
Article
ISSN
0009-2614

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Recombination rates of chlorine atoms in
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## Abstract The recombination of bromine atoms at room temperature has been studied by flash photolysis in the range of 1–100 atm of the inert diluent He, leading to a value for the third‐order rate constant of (1.5 Β± 0.2) Γ— 10^15^ cm^6^/mol^2^.sec. In the presence of NO the recombination is consid

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The recombination of chlorine atoms has been investigated by flash photolysis in the inert gases He, Ne, Ar, Nz, COz, CF4, SiFd, SF6, and C2F6. The pressure dependence of the reaction has been measured between 0.5 and about 100 atm for He, Na, and COZ. Experiments on the NO-catalyzed recombination o

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## Abstract A high‐resolution IR diode laser in conjunction with a Herriot multiple reflection flow‐cell has been used to directly determine the rate coefficients for simple alkanes with Cl atoms at room temperature (298 K). The following results were obtained: __k__(Cl + n‐butane) = (1.91 Β± 0.10)