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The kinetics of ClO formation in the flash photolysis of chlorine–oxygen mixtures

✍ Scribed by R. D. Ashford; N. Basco; J. E. Hunt

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
544 KB
Volume
10
Category
Article
ISSN
0538-8066

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✦ Synopsis

The production o f C l 0 0 and C10 radicals following the flash photolysis of chlorine + oxygen mixtures has been studied. For the mechanism

the following kinetic parameters were measured:

and k:,/c(C100; 250 nm) = 9.7 x 105 cm/sec. Then h:3 = 5.9 X lo9 l/mol.sec, h2 = 1.0 X 10" limol-sec, and t(C100; 250 nm) = 6.1 X 10" l/mol-cm. From limits established for the equilibrium constant K , A H ; (C100) = 94 f 2 kJ/mol.

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