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Reactions of free gold cluster cations with H2O, CH3Cl, and mixtures thereof

✍ Scribed by Sandra M. Lang; Thorsten M. Bernhardt

Book ID
108146653
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
172 KB
Volume
286
Category
Article
ISSN
1387-3806

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## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215–340 nm. By scaling to Οƒ(CH~3~O~2~)~240 nm~ = (4.24 Β± 0.27) Γ— 10^βˆ’18^, the following absorption cross sections were determined: Οƒ(HO~2~)~240 nm~ = 1.29 Β± 0