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Reactions of CO2 with tetrahydroborato copper(I) complexes in moist solvents: Synthesis and reactions of [(phen)2Cu] [(HO)3B(O2CH)] and (phen)(Ph3P)Cu(O2COH) (phen = 1,10-phenanthroline)

โœ Scribed by Girolamo La Monica; M.Angela Angaroni; Franco Cariati; Sergio Cenini


Book ID
108324881
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
753 KB
Volume
143
Category
Article
ISSN
0020-1693

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Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OHยฑH 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A รŠ , b = 107.105(3)ยฐ,