Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê
A new B-Anderson-type heteropoly compound containing binuclear copper(II) coordination ions: synthesis, molecular structure and properties of [Cu 2 (phen) 2 (CH 3 COO) 2 (H 2 O) 2 ] [HAl(OH) 6 (Mo 6 O 18 )]·2.5H 2 O (phen = 1,10-phenanthroline)
✍ Scribed by Wang, Jing-Ping; Zhao, Jun-Wei; Li, Su-Zhi; Niu, Jing-Yang
- Book ID
- 120659843
- Publisher
- Taylor and Francis Group
- Year
- 2006
- Tongue
- English
- Weight
- 421 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0095-8972
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Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,
Two new octadecanuclear clusters [Cu 12 Ln 6 ( 3 -OH) 24 (C 5 H 5 NCH 2 CO 2 ) 12 (H 2 O) 18 ( 9 -NO 3 )] (PF 6 ) 10 (NO 3 ) 7 ' 12H 2 O [Ln III ؍ Sm III (1) or Gd III (2)] have been synthesized and characterized by X-ray di4raction. They are isomorphous and crystallize in the triclinic space grou