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Reactions of carbamylimidazoles with nucleophiles - an example of an intramolecular acyl transfer reaction

✍ Scribed by Ehler, Kenneth W.

Book ID
127099625
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
246 KB
Volume
41
Category
Article
ISSN
0022-3263

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Nucleophile specificity of subtilisin (subtilopeptidase A) was studied via acyl transfer reactions in acetonitrile containing piperidine and 10 vol% of water. Ac-Tyr-OEt was used as acyl donor and a series of amino acid derivatives, diand tripeptides of the general structure Xaa-Gly, Gly-Xaa, Gly-Gl