𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Hydroxylamine anion — an effective α-nucleophile in acyl transfer reactions

✍ Scribed by Yu. S. Simanenko; A. F. Popov; T. M. Prokop'eva; V. A. Savelova; I. A. Belousova


Book ID
112365981
Publisher
Springer
Year
1994
Tongue
English
Weight
264 KB
Volume
30
Category
Article
ISSN
0040-5760

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Nucleophile specificity of subtilisin in
✍ Václav Čeřovský; Hans-Dieter Jakubke 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 581 KB

Nucleophile specificity of subtilisin (subtilopeptidase A) was studied via acyl transfer reactions in acetonitrile containing piperidine and 10 vol% of water. Ac-Tyr-OEt was used as acyl donor and a series of amino acid derivatives, diand tripeptides of the general structure Xaa-Gly, Gly-Xaa, Gly-Gl

The effect of acyl substituents on the α
✍ Ik-Hwan Um; Hyun-Joo Han; Eun-Kyung Chung 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 80 KB

The magnitude of the a-effect for reactions of 4-nitrophenyl substituted benzoates with a pair of anionic nucleophiles is independent of the electronic nature of the acyl substituent, while the one for the corresponding reactions with a pair of neutral nucleophiles increases as the acyl substituent