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Reactions of (C5Me5)M(2,3-dimethyl-1,3-butadiene)Cl (M = Ti, Hf) with symmetrical acetylenes

✍ Scribed by Bart Hessen; Jan H. Teuben


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
262 KB
Volume
107
Category
Article
ISSN
0165-0513

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The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = Β± ; M = Zr,