Synthesis, characterization, and solid-state structures of the 14-electron open metallocenes M[1,5-(Me3Si)2C5H5]2 (M= Ti or Zr)
β Scribed by Robert W. Gedridge; Atta M. Arif; Richard D. Ernst
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 629 KB
- Volume
- 501
- Category
- Article
- ISSN
- 0022-328X
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The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit
The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = Β± ; M = Zr,