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Synthesis, Characterization, and Catalytic Properties of ansa-Zirconocenes [Zr{1-Me2Si(3-η5-C9H5R)2}Cl2] (R = Me, nPr, nBu, and Bz)

✍ Scribed by Carlos Alonso-Moreno; Antonio Antiñolo; Fernando Carrillo-Hermosilla; Antonio Otero; Ana M. Rodríguez; José Sancho; Victoria Volkis; Moris Eisen


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
216 KB
Volume
2006
Category
Article
ISSN
1434-1948

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Synthesis and Reactivity of Alkylzirconi
✍ Antonio Antiñolo; Rafael Fernández-Galán; Beatriz Gallego; Antonio Otero; Sanjiv 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 183 KB

## Abstract The monoalkyl complexes [Zr{Me~2~Si(η^5^‐C~5~Me~4~)(η^5^‐C~5~H~3~R)}(R′)Cl] [R = Me, R′ = CH~2~Ph (1); R = Me, R′ = CH~2~SiMe~3~ (2); R = __i__Pr, R′ = CH~2~Ph (3); R = __i__Pr, R′ = CH~2~SiMe~3~ (4); R = SiMe~3~, R′ = CH~2~Ph (5); R = SiMe~3~, R′ = CH~2~SiMe~3~ (6)] have been synthesiz