𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Dynamic stereochemistry in the titanocene series with central and planar chirality. X-Ray structure and relative configuration of the racemic form (m.p. 186°C) of [(η5-1-Me-2-iPrC5H3)(η5-C5H5)Ti(2,6-Me2C6H3O)Cl]

✍ Scribed by Jack Besançon; Jan Szymoniak; Claude Moïse; Loïc Toupet; Bernard Trimaille

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
844 KB
Volume
491
Category
Article
ISSN
0022-328X

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

The Influence of the Ligands Cp*(η5-C5Me
The Influence of the Ligands Cp*(η5-C5Me5) and Cp(η5-C5H5) on the Stability and Reactivity of Titanocene and Zirconocene Complexes: Reactions of the Bis(trimethylsilyl)acetylene Permethylmetallocene Complexes (η5-C5Me5)2M(η2-Me3SiC2SiMe3), M = Ti, Zr, with H2O and CO2
✍ Paul-Michael Pellny; Vladimir V. Burlakov; Wolfgang Baumann; Anke Spannenberg; U 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 213 KB 👁 1 views

The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,

Synthesis, Structural Characterisation a
Synthesis, Structural Characterisation and Reactivity of New Dinuclear Monocyclopentadienyl Imidoniobium and -tantalum Complexes − X-ray Crystal Structures of [{Nb(η5-C5H4SiMe3)Cl2}2(μ-1,4-NC6H4N)], [{Ta(η5-C5Me5)Cl2}2(μ-1,4-NC6H4N)] and [{Ta(η5-C5Me5)(CH2SiMe3)2}2(μ-1,4-NC6H4N)]
✍ Antonio Antiñolo; Iván Dorado; Mariano Fajardo; Andrés Garcés; Isabel López-Sol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3

Heterometallic analogues of [{M(CO)2(η-C
Heterometallic analogues of [{M(CO)2(η-C5H5)}2] (M = Fe, Ru, Os). The synthesis of the tetracarbonylcyclopentadienylcycloheptatrienyl complexes [M(CO)2(η-C5H5)M′(CO)2(η-C7H7)] (M = Fe, Ru; M′ = Mo, W). Crystal structures of [Ru(CO)2(η-C5H5Mo(CO)2(η-C7H7)] (RuMo) and [Mo(CO)3(μ-η6, η1-C7H7)Ru(CO)2(η-C5Me5)]
✍ Roy L. Beddoes; E.Stephen Davies; Madeleine Helliwell; Mark W. Whiteley 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 1014 KB