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Reactions of Boron Compounds with Metal Chelates and Chelating Agents

✍ Scribed by Prof. Dr. F. Umland


Publisher
John Wiley and Sons
Year
1967
Tongue
English
Weight
139 KB
Volume
6
Category
Article
ISSN
0044-8249

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Since Cram's pioneering workon chelation-control in Grignardtype of addition to chiral alkoxy carbonyl compounds/l/, a number of related reports have appeared. G ' s systematic studies concerning the relative merits of such classical reagents as RMgX, RLi and R CuLi deserve particular attention/2/.

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## A series of six new boron b-diketonates and tropolonates has been synthesized, each compound being crystallized and characterized by spectroscopic methods as well as by X-ray crystallography. A comparative study of the NMR and X-ray data with similar structures from the literature permitted us