✦ LIBER ✦
X-ray crystallographic study of neutral boron chelates with β-diketones and tropolone
✍ Scribed by Herbert Höpfl; Nury Pérez Hernández; Susana Rojas Líma; Rosa Santillan; Norberto Farfán
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 310 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1042-7163
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✦ Synopsis
A series of six new boron b-diketonates
and tropolonates has been synthesized, each compound being crystallized and characterized by spectroscopic methods as well as by X-ray crystallography. A comparative study of the NMR and X-ray data with similar structures from the literature permitted us to develop a detailed evaluation of the bonding in these chelates that lead to several interesting correlations. The present compounds have important physical properties that justify this study.