Reactions of azoesters and dimethyl acetylenedicarboxylate with 3-methyl-1,2,4-triazole-5-thione
✍ Scribed by Gaetano Giammona; Maria Neri; Bianca Carlisi; Aldo Palazzo; Carmelo La Rosa
- Book ID
- 112129922
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1991
- Tongue
- English
- Weight
- 200 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-152X
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📜 SIMILAR VOLUMES
The tandem 1,3 cycloaddition-rearrangement and open chain reactions of 2-aryl-N-aroyl-4,5-dimethyl-1,2,3-triazol-1-imines with DMAD at room temperature and in refluxing toluene are described.
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.034 wR factor = 0.084 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The acyclic C=N double bond of the title compound, C~10~H~10~N~4~S, is __trans__ configured. The molecule is almost planar. The angle between the two rings is just 10.25 (7)°. The crystal packing is stabilized by N—H...S hydrogen bonds and π–π interactions.