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4-[(1E)-Benzyl­ideneamino]-3-methyl-2,4-dihydro-1H-1,2,4-triazole-5-thione

✍ Scribed by Yathirajan, H. S. ;Sarojini, B. K. ;Narayana, B. ;Sunil, K. ;Bolte, Michael

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
197 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The acyclic C=N double bond of the title compound, C~10~H~10~N~4~S, is trans configured. The molecule is almost planar. The angle between the two rings is just 10.25 (7)°. The crystal packing is stabilized by N—H...S hydrogen bonds and π–π interactions.

📜 SIMILAR VOLUMES

4-(2-Hydroxy­benzyl­ideneamino)-3-(1H-1,
4-(2-Hydroxy­benzyl­ideneamino)-3-(1H-1,2,4-triazol-1-ylmeth­yl)-1H-1,2,4-triazole-5(4H)-thione
✍ Hu, Zhi-Qiang ;Shang, Yu-Qing ;Yu, Guan-Ping ;Li, Wei-Hua ;Xu, Liang-Zhong ;Hou, 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 87 KB

In the title compound, C 12 H 11 N 7 OS, the dihedral angles made by the thione-substituted triazole ring with the other triazole ring and the benzene ring are 71.56 (2) and 47.89 (3) , respectively. Inter-and intramolcular hydrogen-bond interactions stabilize the structure.

4-(3-Nitro­benzyl­ideneamino)-3-(1H-1,2,
4-(3-Nitro­benzyl­ideneamino)-3-(1H-1,2,4-triazol-1-ylmeth­yl)-1H-1,2,4-triazole-5(4H)-thione
✍ Shi, Xin-Yan 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 224 KB

In the title compound, C~12~H~10~N~8~O~2~S, the triazole and benzene rings make dihedral angles of 72.16 (2) and 7.39 (3)°, respectively, with the thione-substituted triazole ring. In the crystal structure, intermolecular N—H...N hydrogen bonds link the molecules into chains running in the [101] dir