Reactions of Alkoxy Radicals. VII. The Ethoxy Radical
β Scribed by Wijnen, M. H. J.
- Book ID
- 126264803
- Publisher
- American Chemical Society
- Year
- 1960
- Tongue
- English
- Weight
- 770 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
## Abstract Arrhenius parameters for the decomposition reactions of various alkoxy radicals are evaluated. The recommended values for __tert__βbutoxy radical decomposition reaction are log __A__ (s^β1^) = 14.1, __E__~__a__~ = 15.3 kcal/mol. magnified image The parameters give reasonably selfβconsis
Under tropospheric conditions, the major alkoxy radical removal processes involve reaction with O 2 , unimolecular decomposition, and isomerization [1 -4]. The alkoxy radical isomerizations proceed by a cyclic transition state and, because of the ring strain involved, the 1,4-H shift isomerizations