Reactivity of Alkoxy Radicals in β-Cleavage Reactions
✍ Scribed by O. M. Zarechnaya; I. A. Opeida; A. F. Dmitruk
- Book ID
- 110321731
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2001
- Tongue
- English
- Weight
- 49 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1070-4280
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Under tropospheric conditions, the major alkoxy radical removal processes involve reaction with O 2 , unimolecular decomposition, and isomerization [1 -4]. The alkoxy radical isomerizations proceed by a cyclic transition state and, because of the ring strain involved, the 1,4-H shift isomerizations
CzH50NO was photolyzed with 366 nm radiation at -48, -22, -2.5, 23, 55, 88, and 120°C in a static system in the presence of NO, 0,, and N,. The quantum yield of CH3CH0, (D{CH3CHO), was measured as a function of reaction conditions. The primary photochemical act is (la) CZHSONO + hv -\* CzH50 + NO an
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