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Free-radical reactions of 2-ethoxy-1,3-oxathiolane

โœ Scribed by A. Taganliev; L. Z. Rol'nik; E. V. Pastushenko; S. S. Zlotskii; D. L. Rakhmankulov


Book ID
112358948
Publisher
Springer US
Year
1985
Tongue
English
Weight
109 KB
Volume
21
Category
Article
ISSN
0009-3122

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Radical reduction of cyclic xanthates: F
โœ Jun'ichi Uenishi; Takayuki Kunugi; Yuki Kubo ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 734 KB

AIBN-initiated radical reactions of 5-membered cyclic xanthates, 1,3-oxathiolane-2-thiones, with tributyltin hydride are described. Alkenes are formed at 0.025 M concentration of tributyltin hydride, whereas a higher concentration (0.25 M ) gives 1,3-oxathiolanes. A mixture of alkene and 1,3-0xathio