Reactions of active nitrogen with tellurium atoms
β Scribed by Bernard Vidal; Marie-Paule Bassez; Pierre Goudmand
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 216 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
A number of hydrocarbon cation reactions with N atoms have been measured at near thermal energies ( = 0.1-0.2 eV) in a flow-drift tube experiment. The dominant mechanism is exchange of N for H bonded to a carbon atom, i.e. formation of a CN bond and loss of a CH bond. Formation of a CN bond with los
Detection of atoms by mass spectrometry has been used to study the reactions of hydrogen azide, HN3, with H atoms and active nitrogen, in a fast flow reactor at pressures of about 1 torr. Stoichiometry and products of the H + HN3 reaction have been determined and the rate constant of the initial ste
## Abstract The reaction of nitrogen atoms with methylacetylene has been studied using a fastβflow lowβpressure reactor coupled to a mass spctrometer by a nozzleβbeam sampling system. Hydrogen atom concentrations were measured by ESR analysis. Experimental secondβorder rate constants for the consum
## Abstract The reactions of acetone with tellurium tetrachloride have been studied with the aid of proton, carbonβ13, and telluriumβ125 NMR spectroscopy. In the absence of a proton scavenger, such as sodium hydrogen carbonate, at ambient temperature, a 2 : 1 ratio of acetone to tellurium tetrachlo