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Reactions of 2,2′-diselenobis(N-alkylbenzamides) with peroxides: A free-radical synthesis of Ebselen and related analogues

✍ Scribed by Mei C. Fong; Carl H. Schiesser

Book ID
103406411
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
221 KB
Volume
36
Category
Article
ISSN
0040-4039

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Intramolecular Homolytic Substitution with Amidyl Radicals: A Free-Radical Synthesis of Ebselen and Related Analogues. -Irradiation of the intermediate imidate esters (II) is found to yield the ebselen analogues (III). Presumably, it proceeds via amidyl radicals which undergo subsequent intramolecu