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ChemInform Abstract: Reactions of 2,2′-Diselenobis(N-alkylbenzamides) with Peroxides: A Free-Radical Synthesis of Ebselen and Related Analogues.

✍ Scribed by M. C. FONG; C. H. SCHIESSER

Book ID
112025426
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Stereoselective Synthesis of (±)-α-Kainic Acid Using Free Radical Key Reactions. -The title compound (XI) is obtained via two routes from the highly substituted isocyanide and the isothiocyanate (XII) via the common intermediate (IX). In both routes the key synthons (cf. (IV) and (XIV)) are obtained