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Reactions of 1,2-dihaloethanes with chalcogenide anions

✍ Scribed by N. V. Russavskaya; V. A. Grabel’nykh; E. P. Levanova; E. N. Sukhomazova; L. V. Klyba; E. R. Zhanchipova; A. A. Tatarinova; A. V. Elaev; E. N. Deryagina; N. A. Korchevin; B. A. Trofimov

Book ID
111463972
Publisher
SP MAIK Nauka/Interperiodica
Year
2006
Tongue
English
Weight
594 KB
Volume
42
Category
Article
ISSN
1070-4280

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Reactions of thiolate anions with 2-subs
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Thiolates undergo substitution reactions with 2-substituted-2-nitropropanes by an SRNl mechanism or are oxidised to disulphides by an ionic mechanism.

Reactions of carbenes with anions
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✍ Detlev Sülzle 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 117 KB

CHBrC12, CHC121 and CHBr21 are prepared by a simple method based on REACTIONS OF CARBENES WITH ANIONS Detlev Siilzle the reaction of dichloro or dibromocarbene with the corresponding alkali metal halogenides under phase transfer conditions. Although the reaction of the electrophilic carbenes /l/, C