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Reactions of carbonylmetallate anions with 1-haloalkynes

✍ Scribed by N. A. Ustynyuk; T. V. Filatova; V. N. Vinogradova; L. I. Leont'eva; O. V. Semeikin; L. M. Epshtein; E. S. Shubina; L. N. Saitkulova; E. V. Bakhmutova; A. L. Chistyakov; I. V. Stankevich

Book ID
105596284
Publisher
Springer
Year
1999
Tongue
English
Weight
898 KB
Volume
48
Category
Article
ISSN
1573-9171

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1-chloroalkynes and 1-bromohexyne undergo cycloaddition reactions with ethoxyvinylketeneiron(0) complexes to form chloro and bromocatechols. With most substituents, the halogen is incorporated ortho to the phenolic hydroxyl group regioselectively. With chloroethyne, chlorohexyne, and methyl chloropr