A kinetic and synthetic study of the reaction of benzyl chloride with bromide ion has been performed in microemulsions composed of cetyltrimethylammonium bromide, 1-butanol, water, potassium bromide, and hexane; rates and yields of benzyl bromide formation decreased with increasing hexane content.
Reactions in microemulsion media. Nucleophilic substitution reactions of benzyl and p-alkylbenzyl chlorides
β Scribed by Martin, Craig A.; McCrann, Patrick M.; Ward, Mary Darlene; Angelos, George H.; Jaeger, David A.
- Book ID
- 126440455
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 679 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Gas-phase nucleophilic substitution reactions of Y-benzyl chlorides with X-phenoxide and Xthiophenoxide nucleophiles were investigated theoretically using the PM3 semi-empirical MO method. The Leffler-Grunwald rate-equilibrium and BrΓΈnsted correlations predict that the degree of bond formation in th
Substitution Reactions of Phenanthro[9,triazole with Benzyl Chlorides. -Reaction of the potassium salt of phenanthrotriazole (I) with benzyl chlorides provides the 2-benzylated derivatives (IV) as major and the 1-benzylated derivatives (III) as the minor product. -(YASUDA, G.;