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Reactions at high pressures. [3+2] Dipolar cycloaddition of nitrones with vinyl ethers

โœ Scribed by Dicken, Carl Michael; DeShong, Philip


Book ID
118002118
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
720 KB
Volume
47
Category
Article
ISSN
0022-3263

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Ti(IV) promoted 1, 3-dipolar cycloadditi
โœ Pau Bayoยดn; Pedro de March; Marta Figueredo; Josep Font ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 669 KB

The 1,3-dipolar cycloaddition of nitrones to vinyl ethers is accelerated by Ti(IV) species. The efficiency of the catalyst parallels its complexation capacity. The use of Ti(iprO)2Cl 2 favours the formation of trans cycloadducts, presumably through an endo bidentate complex, in which the metal atom