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Reactions at high pressure 13; volume profiles for the brominolyses of tetra-alkylstannanes.

โœ Scribed by Neil S. Isaacs


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
113 KB
Volume
25
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Reactions at high pressure, part 10: the
โœ Neil S. Isaacs; Paul Van der Beeke ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 109 KB

the intramolecular cyclisation of furans, 3, proceeds with the following activation characteristics: J(R=Et) has EA= 72.5, H=69. 9 kJmo1 -' s" ,62Jf1 , mol-l, d= -25 cm3mol-'. The results confirm the existence of a negative volume contribution from the approach of reagents in intermolecular analogu

Organic reactions at high pressure. A mi
โœ William G Dauben; Richard A Bunce; John M Gerdes; Kevin E Henegar; Allan F Cunni ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 268 KB

A series of hindered and/or labile alcohols has been derivatized with a variety of acylating and silylating agents using pyridine in methylene chloride at 15 kbar (1.5 GPa) pressure to afford excellent yields of protected alcohols at 20 "C, largely without the need for added DMAP. Methoxyethoxymeth