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Reaction Rates of t-Butyl and Pivaloyl Radicals in Solution

✍ Scribed by Hans Schuh; Edwin J. Hamilton Jr.; Henning Paul; Hanns Fischer

Publisher
John Wiley and Sons
Year
1974
Tongue
German
Weight
695 KB
Volume
57
Category
Article
ISSN
0018-019X

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## Abstract The decay of photochemically generated __tert__‐butyl radicals in methylcyclopentane solutions containing chloroform is studied by time‐resolved ESR spectroscopy. In the pure solvent it perfectly follows the second‐order rate law for radical self‐termination. Increasing chloroform conce

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